Engineering metal-organic framework architectures for enhanced carbon dioxide capture

Zeng Wanyi; Huang Minzhong; Chen Bin; Kok Bing Tan; Cai Dongren; Wanchai Pluempanupat; Zhan Guowu

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Engineering metal-organic framework architectures for enhanced carbon dioxide capture

Updated：2026-08-24

- Engineering metal-organic framework architectures for enhanced carbon dioxide capture
- Engineering metal-organic framework architectures for enhanced carbon dioxide capture
- 中国化学工程学报（英文） 2026年94卷第6期页码：331-356
- Affiliations：
  
  Academy of Advanced Carbon Conversion Technology, College of Chemical Engineering, Huaqiao University, Xiamen 361021, China
  Fujian Provincial Key Laboratory of Biomass Low-Carbon Conversion, Huaqiao University, Xiamen 361021, China
  Xiamen Institute of Rare Earth Materials, Haixi Institute, Chinese Academy of Sciences, Xiamen 361021, China
  Department of Chemistry and Center of Excellence for Innovation in Chemistry, Special Research Unit for Advanced Magnetic Resonance, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand
- Author bio：
  
  Corresponding author. E-mail address: gwzhan@hqu.edu.cn(G. Zhan)
- Funds：
  
  the National Natural Science Foundation of China(22322806;22350410389);Additionally, we express gratitude to the Postdoc Innovative Funds(605-50Y24020)
- DOI：
  中图分类号：
- 收稿：2025-09-28，
  
  修回：2025-12-02，
  
  录用：2025-12-25，
  
  网络首发：2026-02-13，
  
  纸质出版：2026-06
- Accepted：
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Zeng Wanyi, Huang Minzhong, Chen Bin, 等. Engineering metal-organic framework architectures for enhanced carbon dioxide capture[J]. 中国化学工程学报（英文）, 2026,94(6):331-356.

Zeng Wanyi, Huang Minzhong, Chen Bin, et al. Engineering metal-organic framework architectures for enhanced carbon dioxide capture[J]. Chinese Journal of Chemical Engineering, 2026, 94(6): 331-356.
Zeng Wanyi, Huang Minzhong, Chen Bin, 等. Engineering metal-organic framework architectures for enhanced carbon dioxide capture[J]. 中国化学工程学报（英文）, 2026,94(6):331-356. DOI：

Zeng Wanyi, Huang Minzhong, Chen Bin, et al. Engineering metal-organic framework architectures for enhanced carbon dioxide capture[J]. Chinese Journal of Chemical Engineering, 2026, 94(6): 331-356. DOI：

摘要

Abstract

The escalating concentration of atmospheric CO

is a major driver of global climate change

necessitating efficient capture technologies. Metal-organic frameworks (MOFs) have emerged as promising adsorbents due to their structural tunability

high surface areas

and porosity. However

their industrial deployment remains constrained by moderate adsorption capacities

limited stability under realistic conditions

selectivity challenges

and high production costs. This review systematically examines rational design strategies for enhancing MOF performance in CO

capture

integrating recent advances in material synthesis

characterization

and computational modeling. We discuss the role of theoretical approaches

including density functional theory

molecular simulations

and machine learning

in predicting adsorption behavior and guiding experimental efforts. Key optimization techniques explored encompass pore engineering

surface functionalization

metal site regulation

defect control

and composite formation. Furthermore

we evaluate selective adsorption mechanisms in complex gas mixtures and assess commercialization pathways

highlighting the importance of economic viability and sustainable synthesis methods. Finally

we outline future research directions aimed at improving cyclic stability

scalability

and industrial applicability

providing a cross-scale perspective on translating laboratory innovat

ions into practical CO

capture applications.

关键词

Keywords

references

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