Experiments and insights of desalination by a freezing/thawing method at low subcooling
Separation Science and Engineering|Updated:2026-01-06
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Experiments and insights of desalination by a freezing/thawing method at low subcooling
Chinese Journal of Chemical EngineeringVol. 28, Issue 12, Pages: 3011-3017(2020)
Affiliations:
1. Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, College of Chemistry & Biology and Environmental Engineering, Xiangnan University,Chenzhou,China,423000
2. Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology,Dalian,China,116024
3. School of Chemistry and Chemical Engineering, Liaocheng University,Liaocheng,China,252059
4. Shandong Provincial Key Laboratory of Molecular Engineering, QiLu University of Technology(Shandong Academy of Sciences),Jinan,China,250353
Jun Chen, Jianjian Wu, Jiafeng Xu, Qing Yuan, Bin Deng, Changzhong Chen, Zhi Li. Experiments and insights of desalination by a freezing/thawing method at low subcooling[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3011-3017.
DOI:
Jun Chen, Jianjian Wu, Jiafeng Xu, Qing Yuan, Bin Deng, Changzhong Chen, Zhi Li. Experiments and insights of desalination by a freezing/thawing method at low subcooling[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3011-3017.DOI: 10.1016/j.cjche.2020.05.012.
Experiments and insights of desalination by a freezing/thawing method at low subcooling
Desalination by freezing/thawing method was a very important method to obtain fresh water from sea water. In this work
desalination by freezing/thawing method was conducted with initial sodium chloride of 3.5 wt% in consideration of stirring speed
freezing time and subcooling. The subcooling ranged from 1.2 K to 4 K. The optimum conditions for desalination in this work were stirring speed of 200 r·min
-1
freezing time of 120 min
and subcooling of 3 K. The results also showed that sodium chloride cannot be effectively removed by once freezing/thawing process. The maximum removal efficiency of sodium chloride was 64.3%. Two major reasons resulting in the impurity of obtained melted water by freezing/thawing method were proposed. The first reason was the inevitable adhesion of salt solution to the surface of ice
which could be removed easily by distilled water flushing. The second reason was that salt solution was heterogeneously wrapped in the accumulated ice
which was difficult to be removed by distilled water flushing. The liquid flushing method was proposed to verify the conjecture
and the results were in accordance with the two reasons mentioned above. Additional method
such as mul
tiple flushing liquid method
was suggested to be used during the freezing/thawing process for effectively removing sodium chloride
and obtaining fresh water.
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