In this study

the thermogravimetric analysis (TGA) method has been used to evaluate the kinetic behavior of biomass

coal and its blends during oxyfuel co-combustion. The thermogravimetric results have been evaluated by the Coats-Redfern method and validated by Criado's method. TG and DTG curves indicate that as the oxygen concentration increases the ignition and burn out temperatures approach a lower temperature region. The combustion characteristic index shows that biomass to coal blends of 28% and 40% respectively can achieve enhanced combustion up to 60% oxygen enrichment. In the devolatilization region

the activation energies for coal and blends reduce while in the char oxidation region

they increase with rise in oxygen concentration. Biomass

however

indicates slightly different combustion characteristic of being degraded in a single step and its activation energies increase with rise in oxygen concentration. It is demonstrated in this work that oxygen enrichment has more positive combustion effect on coal than biomass. At 20% oxygen enrichment

28% and 40% blends indicate activation energy of 132.8 and 125.5 kJ·mol

-1

respectively which are lower than coal at 148.1 kJ·

mol

-1

but higher than biomass at 81.5 kJ·mol

-1

demonstrating synergistic effect of fuel blending. Also

at char combustion step

an increase in activation energy for 28% blend is found to be 0.36 kJ·mol

-1

per rise in oxygen concentration which is higher than in 40% blend at 0.28 kJ·mol

-1

.