Linlin Dai, Lin Hao, Wei Kang, Wei Xu, Ning Shi, Hongyuan Wei. Inhibition of different types of inert dust on aluminum powder explosion[J]. Chinese Journal of Chemical Engineering, 2020, 28(7): 1941-1949.
DOI:
Linlin Dai, Lin Hao, Wei Kang, Wei Xu, Ning Shi, Hongyuan Wei. Inhibition of different types of inert dust on aluminum powder explosion[J]. Chinese Journal of Chemical Engineering, 2020, 28(7): 1941-1949.DOI: 10.1016/j.cjche.2020.02.021.
Inhibition of different types of inert dust on aluminum powder explosion
but the mechanism of aluminum powder explosion is unclear. Therefore
the inhibitive effect of aluminum powder explosion plays a key role. To evaluate the inhibition capacity of different kinds of carbonates and phosphates: NaH
2
PO
4
(NH
4
)
2
HPO
4
NH
4
H
2
PO
4
KHCO
3
and NaHCO
3
on aluminum deflagrations
a standard 20-L spherical chamber was used to determine the explosion severity
characterized by the maximum explosion pressure (
P
max
). New parameters have been proposed: the minimum significant inert concentration (MSIC) and the minimum complete inert concentration (MCIC)
which characterized the effect of inert. Experimental results showed that from the minimum significant inert concentration (MSIC) and the minimum complete inert concentration (MCIC)
phosphate can have a significant inhibiting effect. 40% NaH
2
PO
4
can totally inert the aluminum explosion
and 50% (NH
4
)
2
HPO
4
or 50% NH
4
H
2
PO
4
can also suppress the explosion. Through
simulation
phosphate mainly acts
via
a chemical inhibition pathway
which inhibits the reaction of aluminum powder and oxygen by catalyzing the recombination of H atoms and O atoms. Carbonate performs inhibition in chemically
producing CO
2
diluting the oxygen around the aluminum powder. Studies indicated that the explosion pressure of the mixture decreases as the concentration of inert dust increases. However
when the concentration of carbonates was low
SEEP (suppressant enhanced explosion parameter) phenomenon was found. This research work has a potential industrial application in high hazard aluminum working condition
which can help decrease the explosion pressure and reduce the accident loss.
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