Ismail M. Ahmed, Mostafa M. Hamed, Sayed S. Metwally. Experimental and mathematical modeling of Cr(VI) removal using nano-magnetic Fe3O4-coated perlite from the liquid phase[J]. Chinese Journal of Chemical Engineering, 2020, (6): 1582-1590. DOI: 10.1016/j.cjche.2019.12.027.
DOI:
Ismail M. Ahmed, Mostafa M. Hamed, Sayed S. Metwally. Experimental and mathematical modeling of Cr(VI) removal using nano-magnetic Fe3O4-coated perlite from the liquid phase[J]. Chinese Journal of Chemical Engineering, 2020, (6): 1582-1590. DOI: 10.1016/j.cjche.2019.12.027.DOI:
Experimental and mathematical modeling of Cr(VI) removal using nano-magnetic Fe3O4-coated perlite from the liquid phase
Modification of perlite using nano-magnetic iron oxide was implemented to produce nano-magneticFe
3
O
4
-coated perlite composite (Fe
3
O
4
/Perlite). The prepared composite was characterized using Scanning Electron Microscopy
Fourier-Transform Infrared spectroscopy and Powder X-ray Fluorescence. The potentiality of both perlite and Fe
3
O
4
/Perlite composite to eliminate Cr(VI) from the environmentally relevant water was investigated. The influence of main factors which could affect the adsorption was studied including; pH of medium
shaking time and Cr(VI) ions concentration. The experimental outcome demonstrated that the modification of perlite by nano-magnetic Fe
3
O
4
showed a significantly enhanced Cr(VI) removal efficiency relative to that of unmodified perlite. From the kinetic studies
the experimental data fitted well with the pseudo-second-order model. Moreover
it proposes that Langmuir isotherm is more adequate than the Freundlich isotherm for both perlite and modified perlite. The results recommended that Fe
3
O
4
/Perlite composite had a grea
t potential as an economic and efficient adsorbent of Cr(VI) from contaminated water
which has huge application potential.
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