Yinglu Gu, Shuang Chen, Hui'e Liu, Jun Li, Yutong Liu, Long Wang. Remediation of diesel oil contaminated sand by micro-emulsion[J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 526-531.
DOI:
Yinglu Gu, Shuang Chen, Hui'e Liu, Jun Li, Yutong Liu, Long Wang. Remediation of diesel oil contaminated sand by micro-emulsion[J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 526-531.DOI: 10.1016/j.cjche.2019.07.004.
Remediation of diesel oil contaminated sand by micro-emulsion
Micro-emulsion has unique advantages in repairing diesel oil contaminated sand due to its low interfacial tension and strong solubility. By Winsor phase diagram
it was found that with the increase of salinity
the phase of microemulsion transformed from Winsor I to Winsor III to Winsor II. Under cryogenic electron microscope
it was observed that Winsor I was O/W type
Winsor II was W/O type
and Winsor III type was bi-continuous type. The effect of inorganic salts
alcohol and temperature on the oil removal rate of diesel oil contaminated sand was investigated by static recovery of micro-emulsion precursor. The results showed that for the anionic microemulsion system
with the increase of salinity and alcohols
the oil yield of the upper phase increased first and then decreased
and the two components had a certain compensation effect. For non-ionic micro-emulsion system
with the increase of temperature
the oil yield in the upper phase rose first and then decreased. At the same time
the influence of leaching conditions on oil removal rate was investigated by one-dimensional sand column leaching experiment. It was found that for diesel oil contaminated sand with 15% oil content
when the formulation
was 2.00 wt% SDBS
4.05 wt%
n
-butanol and 0.40 wt% sodium chloride
the optimum leaching conditions were leaching rate of 4 ml·min
-1
and leaching amount of 400 ml. Under such conditions
the oil removal rate was up to 82.84%
that is
the oil content of the sand was reduced to 2.57%. Moreover
the micro-emulsion has good cyclicity
and it can still achieve high oil yield after six cycles.
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