Zizong Wang, Hongqian Liu, Jiming Wang. Optimization of the separation unit of methanol to propylene (MTP) process and its application[J]. Chinese Journal of Chemical Engineering, 2019, 27(5): 1089-1093.
DOI:
Zizong Wang, Hongqian Liu, Jiming Wang. Optimization of the separation unit of methanol to propylene (MTP) process and its application[J]. Chinese Journal of Chemical Engineering, 2019, 27(5): 1089-1093.DOI: 10.1016/j.cjche.2019.01.020.
Optimization of the separation unit of methanol to propylene (MTP) process and its application
Based on a typical gas composition from a methanol-to-propylene (MTP) reactor
and guided by a requirement to recover both propylene and ethylene
three separation strategies are studied and simulated by using PROⅡ package. These strategies are sequential separation
front-end dethanization
and front-end depropanization. The process does not involve an ethylene refrigeration system
using the separated stream as absorbent
and absorbing further the medium-pressure demethanization
and a proprietary technology by combining intercooling oil absorption and throttle expansion. Influences of different process streams as absorbent are studied on energy consumptions
propylene and ethylene recovery percentages
and other key-performance indicators of the separation strategies. Based on a commercial MTP plant with a methanol capacity of 1700 kt·a
-1
the simulated results show that the front-end dethanization using the C
4
mixture as absorbent is the optimal separation strategy
in which the standard fuel oil consumption (a key-performance indicator of energy consumption) is 18.97 kt·h
-1
the total power consumption of two compressors is 22.4 MW
the propylene recovery percentage is 99.70%
and the ethylene recovery percentage is 99.70%. For a further improvement
the pre-dethanization and thermal coupling methods are applied. By using front-end pre-dethanization (partial cutting) with debutanizeroverhead
i.e
. the C4 mixture
as absorbent
the power consumption of the compressors decreases to 19.9 MW
an 11% reduction compared with the clear-cutting method. The energy consumption for the dual compressors for crude gaseous product mixture and main product propylene refrigeration is 16.69 MW
16.55% lower than that of the present MTP industrial plant with the same scale
and a total energy consumption of 20 MW for the triple compressors including product gas mixture compression
and ethylene and propylene refrigeration.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.