The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation

Weili Jiang; Jinxin Chu; Jie Yang; Pengyu Zang; Lijie Gao; Guanglin Zhou; Hongjun Zhou; Huibo Wei

doi:10.1016/j.cjche.2018.05.018

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The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation

Catalysis, Kinetics and Reaction Engineering | Updated：2026-01-06

- The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation
- Chinese Journal of Chemical Engineering Vol. 26, Issue 9, Pages: 1943-1948(2018)
- Affiliations：
  
  1. 2 Department of Chemistry, University of California, Riverside,CA,USA,92521
  2. 3 Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing,China,100871
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.05.018
  CLC：
- Published：2018
- Accepted：
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Weili Jiang, Jinxin Chu, Jie Yang, Pengyu Zang, Lijie Gao, Guanglin Zhou, Hongjun Zhou, Huibo Wei. The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation[J]. Chin.J.Chem.Eng., 2018, 26(9): 1943-1948.
DOI：

Weili Jiang, Jinxin Chu, Jie Yang, Pengyu Zang, Lijie Gao, Guanglin Zhou, Hongjun Zhou, Huibo Wei. The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation[J]. Chin.J.Chem.Eng., 2018, 26(9): 1943-1948. DOI： 10.1016/j.cjche.2018.05.018.

摘要

Abstract

Four monodentate P-ligands and their mixtures (six groups of double-ligand systems

four groups of triple-ligand systems and one group of tetra-ligand system) were used with Rh(acac)(CO)

(acac=acetylacetonate) or Rh (acac)CO(PPh

) as the catalyst in the hydroformylation reaction of 1-butene. It was found that different Rh catalysts showed little difference in the catalysis performance. The general order of catalysis performance is doubleligand system single-ligand system triple-ligand system tetra-ligand system. Some synergistic effect in the double-ligand system was detected which needs a further investigation.

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