One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Chongwen Jiang; Jundong Zhu; Bing Wang; Lu Li; Hong Zhong

doi:10.1016/j.cjche.2018.02.031

Your Location：

Home >

Browse articles >

One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Catalysis | Updated：2026-01-06

- One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6
- Chinese Journal of Chemical Engineering Issue 6, Pages: 1270-1277(2018)
- Affiliations：
  
  1. College of Chemistry and Chemical Engineering, Central South University,Changsha,China,410083
  2. 2 Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University,Changsha,China,410083
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.02.031
  CLC：
- Published：2018
- Accepted：
Scan QR Code
Chongwen Jiang, Jundong Zhu, Bing Wang, et al. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1270-1277.
DOI：

Chongwen Jiang, Jundong Zhu, Bing Wang, et al. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1270-1277. DOI： 10.1016/j.cjche.2018.02.031.

摘要

Abstract

Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method. Various characterization techniques confirm that highly distributed ZrO

nanoparticles and multicoordinated Zr

species are incorporated in the mesoporous composites. One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system. The effects of temperature

reaction time

catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated. It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system

respectively. Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Temperature-dependent pyrolysis product modulation driven by thermal pretreatment of Shendong coal

Migration pathway of nitrogen and phosphorus in municipal sludge during three thermochemical transformation ways

Humification of organic matter and passivation of heavy metals during the hydrothermal carbonization of swine manure

Electrocatalytic glucose oxidation activity of Ni/CNT composites based on low-temperature discharge synthesis

Microwave-assisted dehydration of strontium hydroxide octahydrate: Experimental study and kinetic modeling analysis

Related Author

Qiang Luyao

Bai Boyang

Sun Ming

Song Dengmeng

Hou Boli

Gao Ting

Ma Xiaoxun

Kun Wang

Related Institution

Shaanxi Coal and Chemical Industry Group Shenmu Tianyuan Chemical Industry Co., Ltd, Shenmu

School of Chemical Engineering, Northwest University

College of Chemistry and Materials Science, Weinan Normal University

Shaanxi Engineering Research Center of Green Low-carbon Energy Materials and Processes, Xi'an Shiyou University

College of Chemistry and Chemical Engineering, Xi'an Shiyou University

⁰