Study on the pinene isomerization catalyzed by TiM
Catalysis, Kinetics and Reaction Engineering|Updated:2026-01-06
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Study on the pinene isomerization catalyzed by TiM
Chinese Journal of Chemical EngineeringVol. 26, Issue 12, Pages: 2537-2541(2018)
Affiliations:
Department of Chemical Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University,Shanghai,China,200240
Jionghua Xiang, Zhenghong Luo. Study on the pinene isomerization catalyzed by TiM[J]. Chin.J.Chem.Eng., 2018, 26(12): 2537-2541.
DOI:
Jionghua Xiang, Zhenghong Luo. Study on the pinene isomerization catalyzed by TiM[J]. Chin.J.Chem.Eng., 2018, 26(12): 2537-2541.DOI: 10.1016/j.cjche.2018.02.005.
Study on the pinene isomerization catalyzed by TiM
The isomerization reaction of pinene is one of the most important chemical reactions in the deep processing of pinene. The purpose of this study is to improve the performance of the metatitanic acid by composite. The composite metatitanic acid catalyst TiM was prepared by adding Mn elements in the preparation process. The catalytic performance of TiM was evaluated. Comparison of TiM and metatitanic acid catalyst (Ti-FGP)
the reaction rate of TiM catalyst was faster
and after the reaction
the yield of camphene and tricyclene increased about 1%. The catalysts were characterized by an SEM
FT-IR and laser particle size analyzer. The results show that the pinene isomerization reaction requires the synergistic action of the Brönsted acid and Lewis acid. Brönsted acid has great influence on the activity of catalyst
and Lewis acid has a great influence on the selectivity of the catalyst. The structure and morphology of the catalyst have a certain effect on the selectivity of pinene isomerization reaction.
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