Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration

Jingyong Liu; Chao Liu; Guang Sun; Wuming Xie; Xiao'e Dang; Jiahong Kuo; Kenlin Chang; Jian Sun; Shuiyu Sun; Musa Buyukada; Fatih Evrendilek

doi:10.1016/j.cjche.2017.10.019

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Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration

Energy, Resources and Environmental Technology | Updated：2026-01-06

- Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration
- Chinese Journal of Chemical Engineering Vol. 26, Issue 5, Pages: 1160-1170(2018)
- Affiliations：
  
  1. 2 Shaanxi Key Laboratory for Gold and Resources, School of Metallurgical Engineering, Xi'an University of Architecture and Technology,Xi'an,China,710055
  2. 3 Institute of Environmental Engineering, National Sun Yat-Sen University, Kaohsiung,China,80424
  3. 4 Department of Environmental Engineering, Abant Izzet Baysal University,Bolu,Turkey,14052
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2017.10.019
  CLC：
- Published：2018
- Accepted：
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Jingyong Liu, Chao Liu, Guang Sun, Wuming Xie, Xiao'e Dang, Jiahong Kuo, Kenlin Chang, Jian Sun, Shuiyu Sun, Musa Buyukada, Fatih Evrendilek. Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration[J]. Chin.J.Chem.Eng., 2018, 26(5): 1160-1170.
DOI：

Jingyong Liu, Chao Liu, Guang Sun, Wuming Xie, Xiao'e Dang, Jiahong Kuo, Kenlin Chang, Jian Sun, Shuiyu Sun, Musa Buyukada, Fatih Evrendilek. Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration[J]. Chin.J.Chem.Eng., 2018, 26(5): 1160-1170. DOI： 10.1016/j.cjche.2017.10.019.

摘要

Abstract

Thermodynamic equilibrium calculations were performed to reveal effects of interactions among Cl

P and other minerals on Cu migration. Our results showed that HCl(g)

(g) and (P

)

(g) were released from the sewage sludge co-incineration. Cl was found to weaken adsorption of Cu by Al

CaO and Fe

while S delayed reactions of Fe

and Al

with Cu

with P having no effect on reactions between the minerals and Cu. Among the coupled systems of Cl

S and P

the co-existences of Cl and S

and Cl

S and P were determined to inhibit Cu volatilization

and the co-existence of Cl and P had an enhancing effect. Cu migration was affected only by S in the S and P system. With the SiO

CaO and Al

system

both Cl alone and Cl and P led to failed reactions between the minerals and Cu. In the systems of S

S and Cl

S and P

and S

Cl and P

the migration behavior of Cu was mainly affected by S at low temperatures and by Cl at high temperatures

whereas P had no effect on

Cu migration during the entire process.

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