Effects of nitrogen doping on surface-enhanced Raman scattering (SERS) performance of bicrystalline TiO<sub>2</sub> nanofibres

Haijuan Zhang; Rong An; Xinghong Ji; Yihui Dong; Fan Pan; Chang Liu; Xiaohua Lu

doi:10.1016/j.cjche.2017.05.020

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Effects of nitrogen doping on surface-enhanced Raman scattering (SERS) performance of bicrystalline TiO₂ nanofibres

Materials and Product Engineering | Updated：2026-01-06

- Effects of nitrogen doping on surface-enhanced Raman scattering (SERS) performance of bicrystalline TiO₂ nanofibres
- Chinese Journal of Chemical Engineering Vol. 26, Issue 3, Pages: 642-647(2018)
- Affiliations：
  
  2 Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, No. 200, Xiaolingwei,Nanjing,China,210094
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2017.05.020
  CLC：
- Published：2018
- Accepted：
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nanofibres[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 642-647.
DOI：

nanofibres[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 642-647. DOI： 10.1016/j.cjche.2017.05.020.

摘要

Abstract

In this work

we successfully synthesized bicrystalline anatase/TiO

(B) nanofibre and used it as active substrate for surface-enhanced Raman scattering (SERS) applications. The bicrystalline structured TiO

substrates provide additional charge transfer across the anatase-TiO

(B) interface and thus enhanced activity compared to the pure single crystalline phase. With an effort to further increase the sensitivity of SERS

nitrogen element was doped into bicrystalline anatase/TiO

(B) nanofibres (N-TiO

) and higher SERS enhancement was achieved. The nitrogen content was controlled by tuning the calcination temperature of titanate precursor at 500

600 and 700℃

respectively. The sample calcined at 600℃ (NT600) acquires the highest percentage of nitrogen element due to its open pore structure that facilitates the diffusion of nitrogen during calcination. Raman intensity depends on the amount of nitrogen doping

thus NT600 exhibited the best SERS activity. The doped nitrogen in TiO

facilitates the charge transfer between TiO

and probing molecules and thus suppresses the electron-hole recombina

tion. This work provides a new perspective on the design of efficient TiO

SERS active substrate and is expected to be valuable for adsorbate detection on semiconductor surface.

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Effects of nitrogen doping on surface-enhanced Raman scattering (SERS) performance of bicrystalline TiO2 nanofibres

DOI：10.1016/j.cjche.2017.05.020

摘要

Abstract

关键词

Keywords

references

Effects of nitrogen doping on surface-enhanced Raman scattering (SERS) performance of bicrystalline TiO₂ nanofibres