A new nanocluster polyoxomolybdate[Mo36O110(NO)4(H2O)14]·52H2O: Synthesis, characterization and application in oxidative degradation of common organic dyes

Mojtaba Amini; Mostafa Khaksar; Arkady Ellern; L. Keith Woo

doi:10.1016/j.cjche.2017.03.031

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A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes

Catalysis, kinetics and reaction engineering | Updated：2026-01-06

- A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes
- Chinese Journal of Chemical Engineering Vol. 26, Issue 2, Pages: 337-342(2018)
- Affiliations：
  
  2 Chemistry Department, Iowa State University, Ames,IA,USA,50011-3111
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2017.03.031
  CLC：
- Published：2018
- Accepted：
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O DOI： 10.1016/j.cjche.2017.03.031.

摘要

Abstract

Polyoxomolybdate[Mo

110

(NO)

]

·52H

O was synthesized by a simple one-pot procedure through reducing an acidified mixture of Na

MoO

·2H

O and NH

OH·HCl. In order to create a heterogeneous catalyst system

the polyoxomolybdate was pillared with MgAl-LDH-NO

by direct ion exchange. These novel materials were carefully analyzed by various chemico-physical methods. The catalytic degradation of methylene blue (MB) and rhodamine B (RB) as common dyes in the presence of MgAl-LDH-1 nanoparticles with aqueous hydrogen peroxide

as an oxidizing agent was studied in aqueous solution at room temperature. More importantly

the catalyst can be recovered and reused efficiently up to five consecutive cycles with negligible loss of catalytic activity.

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