Controllable synthesis of metallic Bi from commercial Bi2O3 via one-pot solvothermal reduction method

Lei Yang; Yangyang Zhang; Hua Li; Hezhou Liu

doi:10.1016/j.cjche.2016.11.002

Your Location：

Home >

Browse articles >

Controllable synthesis of metallic Bi from commercial Bi₂O₃ via one-pot solvothermal reduction method

Catalysis, kinetics and reaction engineering | Updated：2026-01-06

- Controllable synthesis of metallic Bi from commercial Bi₂O₃ via one-pot solvothermal reduction method
- Chinese Journal of Chemical Engineering Vol. 25, Issue 9, Pages: 1202-1206(2017)
- Affiliations：
  
  State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University,Shanghai,China,200240
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.11.002
  CLC：
- Published：2017
- Accepted：
Scan QR Code
O
DOI：

O DOI： 10.1016/j.cjche.2016.11.002.

摘要

Abstract

Metallic bismuth crystal is one important and interesting semimetal that has attracted great attention owing to its unique thermal and electrical properties. Herein

we report a facile

green

cost-effective and sustainable solvothermal process using ethanol

glycol

isopropanol

phenylcarbinol as solvent and commercial Bi

as the starting material to produce high-purity metallic Bi with tunable morphologies on large scale. It is found that all alcohols are capable of reducing Bi

to Bi and the reducibility of glycol is proved to be the strongest. The highest purity of the resultant Bi is calculated to be 99.74%. What's more

the morphology of final Bi particles is controllable by adding various types and concentrations of additives. As a consequence

our work lays the root for the large scale solvothermal production of high-purity Bi particles with various regular morphologies.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Coupling of palladium nanoparticles with biofilm improved co-reduction of chromium(VI) and nitrate

Properties evolutions during carbonization of carbon foam using lignin as sole precursor

One-step preparation of efficient cuprous chloride catalyst for direct synthesis of trimethoxysilane

The dual action of N2 on morphology regulation and mass-transfer acceleration of CO2 hydrate film

Green-synthesized, biochar-supported nZVI from mango kernel residue for aqueous hexavalent chromium removal: Performance, mechanism and regeneration

Related Author

Chengyang Wu

Siqing Xia

Qiyuan Pang

Suyun Xu

Hongbo Liu

Chen Liang

Weiqiang Chen

Linghong Yin

Related Institution

State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University

School of Intelligent Emergency Management, University of Shanghai for Science and Technology

School of Environment and Architecture, University of Shanghai for Science and Technology

Laboratory of Lignin-based Materials, College of Life Sciences, Qingdao Agricultural University

College of Chemistry and Pharmacy, Qingdao Agricultural University

⁰