Yincong Liu, Lingjun Zhu, Xiaoliu Wang, Shi Yin, Furong Leng, Fan Zhang, Haizhou Lin, Shurong Wang. Catalytic methanation of syngas over Ni-based catalysts with different supports[J]. , 2017, 25(5): 602-608.
DOI:
Yincong Liu, Lingjun Zhu, Xiaoliu Wang, Shi Yin, Furong Leng, Fan Zhang, Haizhou Lin, Shurong Wang. Catalytic methanation of syngas over Ni-based catalysts with different supports[J]. , 2017, 25(5): 602-608.DOI: 10.1016/j.cjche.2016.10.019.
Catalytic methanation of syngas over Ni-based catalysts with different supports
摘要
Abstract
Co-precipitation method was selected for the preparation of Ni/Al
2
O
3
Ni/ZrO
2
and Ni/CeO
2
catalysts
and their performances in methanation were investigated in this study. The structure and surface properties of these catalysts were characterized by BET
XRD
H
2
-TPD
TEM and H
2
-TPR. The results showed that the catalytic activity at low temperature followed the order:Ni/Al
2
O
3
Ni/ZrO
2
Ni/CeO
2
. Ni/Al
2
O
3
catalyst presented the best catalytic performance with the highest CH
4
selectivity of 94.5%. The characterization results indicated that the dispersion of the active component Ni was the main factor affecting the catalytic activity and the one with higher dispersion gave better performance.
关键词
Keywords
references
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