Catalytic ozonation of thymol in reverse osmosis concentrate with core/shell Fe3O4@SiO2@Yb2O3 catalyst: Parameter optimization and degradation pathway
摘要
Abstract
In this work
a novel catalyst of Fe
3
O
4
@SiO
2
@Yb
2
O
3
was prepared and the degradation of thymol in reverse osmosis concentrate using ozonation was explored. The operational parameters
such as ozone dosage (8-48 mg·min
-1
)
initial thymol concentration (20-100 mg·L
-1
)
initial pH value (3-11)
and catalyst Fe
3
O
4
@SiO
2
@Yb
2
O
3
dosage (0.2-1.0 g)
were studied focusing on the thymol degradation and COD removal. The results indicated that the increase in ozone dosage
initial pH value
and Fe
3
O
4
@SiO
2
@Yb
2
O
3
dosage accelerated the thymol degradation and COD removal
while the increase in initial thymol concentration hampered the effect of ozonation. A pathway of thymol degradation by catalytic ozonation was proposed based on the intermediates detected by gas chromatography-mass spectrometer and ion chromatography. This paper can provide basic data and technical alternative for pollutant re
moval from reverse osmosis concentrate by ozonation.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.
Adsorption and Ozonation Kinetic Model for Phenolic Wastewater Treatment
Controllable synthesis of Ni3S2/V3S4@NF-xF(x=0, 4, 8) catalysts for efficient hydrogen production in seawater and urea electrolyte
Synthesis of methyl diphenylmethane dicarbamate by methyl phenylcarbamate condensation catalyzed by NKC-9: Non-phosgene preparation of key precursors for diphenylmethane diisocyanate
CaO-stabilized tetragonal ZrO2 support for high-performance Ni—Fe alloy catalysts in dry reforming of methane
Microfluidic extraction of phenolic compounds from wastewater in the straight/helical/in-plane spiral microchannels
Related Author
Wongsarivej Pratarn
Tongprem Pornsiri
Swasdisevi Thanit
Charinpanitkul Tawatchai
Tanthapanichakoon Wiwut
Wen Wei
Meng Xiangyu
Liu Min
Related Institution
National Nanotechnology Center, Thailand Science Park, Klong Luang, Pathumthani
School of Energy, Environment and Materials, King Mongkut’s University of Technology Thonburi, 126 Pracha u-tid Rd.
Center of Excellence in Particle Technology, Faculty of Engineering, Chulalongkorn University, Payathai Rd., Wangmai, Pathumwan
Department of Chemistry, Xinzhou Normal University
Henan Provincial Key Laboratory of Nanocomposites and Applications, Institute of Nanostructured Functional Materials, Huanghe Science and Technology College