Measurement and calculation of solubility of quinine in supercritical carbon dioxide

Fatemeh Zabihi; Mehrdad Mirzajanzadeh; Jingfu Jia; Yaping Zhao

doi:10.1016/j.cjche.2016.10.003

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Measurement and calculation of solubility of quinine in supercritical carbon dioxide

Chemical Engineering Thermodynamics | Updated：2026-01-06

- Measurement and calculation of solubility of quinine in supercritical carbon dioxide
- Chinese Journal of Chemical Engineering Vol. 25, Issue 5, Pages: 641-645(2017)
- Affiliations：
  
  1. Department of Chemical Engineering, Islamic Azad University, Ayatollah Amoli Branch Amol,Iran
  2. Department of Chemical Engineering, Islamic Azad University, Tehran Science and Research Branch, Tehran,Iran
  3. School of Chemistry & Chemical Engineering, Shanghai Jiaotong University,Shanghai,China,200240
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.10.003
  CLC：
- Published：2017
- Accepted：
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Fatemeh Zabihi, Mehrdad Mirzajanzadeh, Jingfu Jia, Yaping Zhao. Measurement and calculation of solubility of quinine in supercritical carbon dioxide[J]. , 2017, 25(5): 641-645.
DOI：

Fatemeh Zabihi, Mehrdad Mirzajanzadeh, Jingfu Jia, Yaping Zhao. Measurement and calculation of solubility of quinine in supercritical carbon dioxide[J]. , 2017, 25(5): 641-645. DOI： 10.1016/j.cjche.2016.10.003.

摘要

Abstract

Solubility of quinine in supercritical carbon dioxide (SCCO

) was experimentally measured in the pressure range of 8 to 24 MPa

at three constant temperatures:308.15 K

318.15 K and 328.15 K. Measurement was carried out in a semi-dynamic system. Experimental data were correlated by iso-fugacity model (based on cubic equations of state

CEOS)

Modified Mendez-Santiago-Teja (MST) and Modified Bartle semi-empirical models. Two cubic equations of state:Peng-Robinson (PR) and Dashtizadeh-Pazuki-Ghotbi-Taghikhani (DPTG) were adopted for calculation of equilibrium parameters in CEOS modeling. Interaction coefficients (

) of van der Waals (vdW) mixing rules were considered as the correlation parameters in CEOS-based modeling and their contribution to the accuracy of model was investigated. Average Absolute Relative Deviation (AARD) between correlated and experimental data was calculated and compared as the index of validity and accuracy for different modeling systems. In this basis it was realized that the semi-empirical equations especially Modified MST can accurately support the theoretical studies on phase equilibrium behavior of quinine-SCCO

media. Among the cubic equations of state DPGT within two-parametric vdW mixing rules provided the best data fitting and PR within one-parametric vdW mixing rules demonstrated the highest deviation respecting to the experimental data. Overall

in each individual modeling system the best fitting was observed on the data points attained at 318 K

which could be perhaps due to the moderate thermodynamic state of supercritical phase.

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