the impact of internal heat integration upon process dynamics and controllability by superposing reactive section onto stripping section
relocating feed locations
and redistributing catalyst within the reactive section is explored based on a hypothetical ideal reactive distillation system containing an exothermic reaction:A+B↔C+D. Steady state operation analysis and closed-loop controllability evaluation are carried out by comparing the process designs with and without the consideration of internal heat integration. For superposing reactive section onto stripping section
favorable effect is aroused due to its low sensitivities to the changes in operating condition. For ascending the lower feed stage
somewhat detrimental effect occurs because of the accompanied adverse internal heat integration and strong sensitivity to the changes in operating condition. For descending the upper feed stage
serious detrimental effect happens because of the introduced adverse internal heat integration and strong sensitivity to the changes in operating condition. For redistributing catalyst in the reactive section
fairly small negative influence is aroused by the sensitivity to the changes in operating condition. When reinforcing internal heat integration with a combinatorial use of these three strategies
the decent of the upper feed stage should be avoided in process development. Although the conclusions are derived based on the hypothetical ideal reactive distillation column studied
they are considered to be of general significance to the design and operation of other reactive distillation columns.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.