Xiang Hu, Zhao Cheng. Removal of diclofenac from aqueous solution with multi-walled carbon nanotubes modified by nitric acid[J]. , 2015, 23(9): 1551-1556.
DOI:
Xiang Hu, Zhao Cheng. Removal of diclofenac from aqueous solution with multi-walled carbon nanotubes modified by nitric acid[J]. , 2015, 23(9): 1551-1556.DOI: 10.1016/j.cjche.2015.06.010.
Removal of diclofenac from aqueous solution with multi-walled carbon nanotubes modified by nitric acid
摘要
Abstract
Modified multi-walled carbon nanotubes (MWCNTs) were used as adsorbents for removal of diclofenac. The reaction conditions were examined. Langmuir
Freundlich
Temkin
and Dubinin-Radushkevich isotherm models were applied to determine appropriate equilibrium expression. The results show that the experimental data fit the Freundlich equation well. Thermodynamic parameters show that the adsorption process is spontaneous and exothermic. The kinetic study indicates that the adsorption of diclofenac can be well described with the pseudo-second-order kinetic model and the process is controlled by multiple steps.
关键词
Keywords
references
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