Jing Fang, Rui Zhao, HuiWang, Chunli Li, Jing Liu. Salting-out effect of ionic liquids on isobaric vapor-liquid equilibrium of acetonitrile-water system[J]. Chin.J.Chem.Eng., 2015, 23(8): 1369-1373.
DOI:
Jing Fang, Rui Zhao, HuiWang, Chunli Li, Jing Liu. Salting-out effect of ionic liquids on isobaric vapor-liquid equilibrium of acetonitrile-water system[J]. Chin.J.Chem.Eng., 2015, 23(8): 1369-1373.DOI: 10.1016/j.cjche.2015.04.011.
Salting-out effect of ionic liquids on isobaric vapor-liquid equilibrium of acetonitrile-water system
摘要
Abstract
This paper presents the vapor-liquid equilibrium (VLE) data of acetonitrile-water system containing ionic liquids (ILs) at atmospheric pressure (101.3 kPa). Since ionic liquids dissociate into anions and cations
the VLE data for the acetonitrile + water + ILs systems are correlated by salt effect models
Furter model and improved Furter model. The overall average relative deviation of Furter model and improved Furter model is 5.43% and 4.68%
respectively. Thus the salt effect models are applicable for the correlation of IL containing systems. The salting-out effect theory can be used to explain the change of relative volatility of acetonitrile-water system.
关键词
Keywords
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