Clean production of chlorine from hydrogen chloride with Mn-compound as intermediate

Gang Yang; Yong Sun; Jinping Zhang; Zuohu Li; Yunshan Wang

doi:10.1016/j.cjche.2014.11.015

Your Location：

Home >

Browse articles >

Clean production of chlorine from hydrogen chloride with Mn-compound as intermediate

能源、资源与环境技术 | Updated：2026-01-06

- Clean production of chlorine from hydrogen chloride with Mn-compound as intermediate
- Chinese Journal of Chemical Engineering Vol. 23, Issue 2, Pages: 435-440(2015)
- Affiliations：
  
  1. National Engineering Laboratory of Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences,Beijing,China,100190
  2. Department of Chemical Engineering, Monash University,VIC,Australia,3800
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2014.11.015
  CLC：
- Published：2015
- Accepted：
Scan QR Code
Gang Yang, Yong Sun, Jinping Zhang, Zuohu Li, Yunshan Wang . Clean production of chlorine from hydrogen chloride with Mn-compound as intermediate[J]. , 2015, 23(2): 435-440.
DOI：

Gang Yang, Yong Sun, Jinping Zhang, Zuohu Li, Yunshan Wang . Clean production of chlorine from hydrogen chloride with Mn-compound as intermediate[J]. , 2015, 23(2): 435-440. DOI： 10.1016/j.cjche.2014.11.015.

摘要

Abstract

A new process is developed by using compound Mn as intermediate to produce Cl

from HCl

with the following steps. (1) HCl steam is decomposed by intermediate Mn

to produce Cl

and MnCl

at 500℃. (2) Produced MnCl

is oxidized by water steam to produce MnO at 450℃. (3) The MnO compound is oxidized by air to yield Mn

. The X-ray diffraction (XRD) crystallite characterization results indicate the high conversion in each step under the optimum experimental conditions. Long term experiments for continuous conversion of HCl to Cl

by using Mn

as intermediate in a fixed bed reactor indicate that over 90% of HCl could be converted to Cl

on stream of 30 h. The production of Cl

fromHClwithMn compound as an intermediate and atmospheric steam is a feasible and recyclable process.

关键词

Keywords

references

Views

158

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Controllable synthesis of novel nanoporous manganese oxide catalysts for the direct synthesis of imines from alcohols and amines

Localized Corrosion and Phase Transformation of Simulated Archaeological Iron

Experimental and numerical studies of holdup and velocity behavior for inclined bubbly oil-water pipe flows

CFD-PBM simulation of liquid-liquid dispersions in an industrial pulsed disc and doughnut column with directly measured breakup and coalescence kernels

Dual-site engineering of Ga-modified HZSM-5 towards efficient propane aromatization

Related Author

Fushan Chen

Songlin Zhao

Tao Yang

Taotao Jiang

Jun Ni

Houfeng Xiong

Qunfeng Zhang

Xiaonian Li

Related Institution

Industrial Catalysis Institute of Zhejiang University of Technology

Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University

School of Pharmaceutical and Chemical Engineering, Taizhou University

School of Material Science and Engineering, Beijing University of Chemical Technology

⁰