ITQ-2 zeolites were prepared by sequential alkali-swelling and ultrasonic-delamination of precursor MCM-22 and characterized by X-ray powder diffraction

scanning electron microscopy

nitrogen adsorption-desorption

ammonia temperature-programmed desorption and in-situ Fourier-transform infrared spectroscopy. The delamination induced a change in the morphology of ITQ-2 zeolites from aggregated thin platelets to scattered platelets

together with a significant increase in external specific surface area

which reached a plateau at the ultrasonic treatment time of 3 h. The catalytic cracking of n-dodecane over ITQ-2 zeolites was evaluated with ITQ-2 coated on the inside wall of a tubular reactor at 550℃ and 4 MPa. The sample obtained by ultrasonic treatment of 3 h (ITQ-2-3) gave the highest initial conversion of n-dodecane

whereas those of 5 h and 1 h gave the conversion even lower than MCM-22

which was in agreement with the trend of the ratio of strong Lewis acid to the total acid amount. Although the amount of cokes deposited on ITQ-2-3 was larger than that on MCM-22

the former deactivated slowly

suggesting that a large external specific surface area benefits the stability of zeolite coatings.