Yali Zhang, Xianjin Yu, Qinglong Wang, Zhijun Jiang, Tao Fang. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution[J]. Chin.J.Chem.Eng., 2015, 23(4): 646-651.
DOI:
Yali Zhang, Xianjin Yu, Qinglong Wang, Zhijun Jiang, Tao Fang. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution[J]. Chin.J.Chem.Eng., 2015, 23(4): 646-651.DOI: 10.1016/j.cjche.2014.01.003.
Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution
摘要
Abstract
Removal of zinc fromcyanide barren solution is obligatory for its reuse in leach process. Batch experiments were carried out to evaluate the adsorption capacity of resins under different experimental conditions
including concentration
resin amount
initial pH
contact time and temperature. More than 99% of adsorption was achieved under the optimal condition. High adsorption rates on the resin were observed at the beginning and plateau values were obtained in 60 min. The thermodynamic parameters (free energy change ΔG
enthalpy change ΔS and entropy change ΔH) for the adsorption were evaluated. The adsorption kinetic mechanism was studied with four models. The experimental results show that the adsorption follows the Langmuir isotherm and the kinetics follows the pseudo-second-order model.
关键词
Keywords
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