Synthesis of a Novel Solid Acid with both Sulfonic and Carbonyl Acid Groups and Its Catalytic Activities in Acetalization

程欲晓; 周宇艳; 张继东; 费旭东; 马腾洲; 梁学正

doi:10.1016/S1004-9541(14)60048-3

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Synthesis of a Novel Solid Acid with both Sulfonic and Carbonyl Acid Groups and Its Catalytic Activities in Acetalization

催化、动力学与反应工程 | Updated：2026-01-06

- Synthesis of a Novel Solid Acid with both Sulfonic and Carbonyl Acid Groups and Its Catalytic Activities in Acetalization
- Chinese Journal of Chemical Engineering Vol. 22, Issue 3, Pages: 312-3171004-954160048-3(2014)
- Affiliations：
  
  2 Institute of Applied Chemistry, Shaoxing University,Shaoxing,China,312000
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(14)60048-3
  CLC：
- Published：2014
- Accepted：
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CHENG Yuxiao, ZHOU Yuyan, ZHANG Jidong, FEI Xudong, MA Tengzhou, LIANG Xuezheng. Synthesis of a Novel Solid Acid with both Sulfonic and Carbonyl Acid Groups and Its Catalytic Activities in Acetalization[J]. Chin.J.Chem.Eng., 2014, 22(3): 312-317.
DOI：

CHENG Yuxiao, ZHOU Yuyan, ZHANG Jidong, FEI Xudong, MA Tengzhou, LIANG Xuezheng. Synthesis of a Novel Solid Acid with both Sulfonic and Carbonyl Acid Groups and Its Catalytic Activities in Acetalization[J]. Chin.J.Chem.Eng., 2014, 22(3): 312-317. DOI： 10.1016/S1004-9541(14)60048-3.

摘要

Abstract

The novel solid acid with both sulfonic and carbonyl acid groups has been synthesized from 3-((2-sulfoethoxy) carbonyl)acrylic acid and tetraethyl orthosilicate (TEOS). The catalytic activities were investigated through the acetalization. The results showed that the novel solid acid was very efficient for the reactions with the high yields. The high acidity

high stability and reusability were the key feature of the novel solid acid. Moreover

the sulfonic and carbonyl acid groups could cooperate during the catalytic process

which improved its catalytic activities. The catalyst shows recyclability

and hold great potential for replacement of homogeneous catalysts.

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