Efficient C—N Formation for Preparing α-Branched Primary Amines by Recycled Intramolecular Reactions of 1,8-Naphthosultone Using Ammonia as Nitrogen Source

周新锐; 陈洁; 曾小萍; 刘季红; Istvan E. Markó

doi:10.1016/S1004-9541(14)60037-9

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Efficient C—N Formation for Preparing α-Branched Primary Amines by Recycled Intramolecular Reactions of 1,8-Naphthosultone Using Ammonia as Nitrogen Source

催化、动力学与反应工程 | Updated：2026-01-06

- Efficient C—N Formation for Preparing α-Branched Primary Amines by Recycled Intramolecular Reactions of 1,8-Naphthosultone Using Ammonia as Nitrogen Source
- Chinese Journal of Chemical Engineering Vol. 22, Issue 4, Pages: 405-4101004-954160037-9(2014)
- Affiliations：
  
  2 Laboratory of Organic and Medicinal Chemistry, Université catholique de Louvain, Place Louis Pasteur 1, B-1348-la-Neuve,Belgium
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(14)60037-9
  CLC：
- Published：2014
- Accepted：
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-Branched Primary Amines by Recycled Intramolecular Reactions of 1,8-Naphthosultone Using Ammonia as Nitrogen Source[J]. Chinese Journal of Chemical Engineering, 2014, 22(4): 405-410.
DOI：

-Branched Primary Amines by Recycled Intramolecular Reactions of 1,8-Naphthosultone Using Ammonia as Nitrogen Source[J]. Chinese Journal of Chemical Engineering, 2014, 22(4): 405-410. DOI： 10.1016/S1004-9541(14)60037-9.

摘要

Abstract

Amination of tertiary and secondary alcohols using aqueous ammonia as nitrogen source was carried out by a process with recyclable intramolecular reaction of 1

8-naphthosultone

which lead to α-branched primary amines. Sulfonic resin serves as the heterogeneous catalyst for C—N bond formation and protects the neighboring hydroxyl group until the required hydrolysis starts in the alkaline solution. The process can be conducted under mild conditions

no additional solvent is needed and no overreaction to secondary or tertiary amines occurs.

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