Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

李杰; 林晓; 宁朋歌; 曹宏斌; 张懿; John C. Crittenden

doi:10.1016/S1004-9541(14)60016-1

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Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

化工热力学 | Updated：2026-01-06

- Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T
- Chinese Journal of Chemical Engineering Vol. 22, Issue 1, Pages: 89-971004-954160016-1(2014)
- Affiliations：
  
  1. 2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences,Beijing,China,100190
  2. 3 Graduate University of Chinese Academy of Sciences,Beijing,China,100049
  3. 4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology,GA,Atlanta,USA,30332
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(14)60016-1
  CLC：
- Published：2014
- Accepted：
Scan QR Code
LI Jie, LIN Xiao, NING Pengge, CAO Hongbin, ZHANG Yi, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chin.J.Chem.Eng., 2014, 22(1): 89-97.
DOI：

LI Jie, LIN Xiao, NING Pengge, CAO Hongbin, ZHANG Yi, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chin.J.Chem.Eng., 2014, 22(1): 89-97. DOI： 10.1016/S1004-9541(14)60016-1.

摘要

Abstract

The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H

S removal. The solubility of H

S in JM-T was measured at 298

313

333

353

and 368 K with H

S partial pressures from 20 to 760 kPa and H

S loading from 0.02 to 0.8 mol H

S per mol JM-T. Relevant physical properties

such as density

viscosity and dielectric constant

of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore

the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

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