In situ capping is an attractive and cost-effective method for remediation of contaminated sediments

but few studies on enhancing contaminant degradation in sediment caps have been reported

especially for chlorinated benzenes. Electrically enhanced bioactive barrier is a new process for in situ remediation for reducible compounds in soil or sediments. The primary objective of this study is to determine if electrodes in sediment could create a redox gradient and provide electron acceptor/donor to stimulate degradation of chlorinated contaminant. The results demonstrate that graphite electrodes lead to sustainable evolution of hydrogen

displaying zero-order kinetics in the initial stages with different voltages. The constant rates of hydrogen evolution at 3

4

and 5 V are 1.05

2.54

and 4.3 nmol·L

-

1

·d

-

1

respectively. Even higher voltage can produce more hydrogen

but it could not keep long time because the over potentials on electrode surfaces prevent its function. The study shows that 4 V is more appropriate for hydrogen evolution. The measured and evaluated concentration of 1

2

3

5-tetrachlorobenzene in pore water of sediment and concentration of sulfate show that dechlorination is inhibited at higher concentratio

n of sulfate.