Kinetics and Modeling of Chemical Leaching of Sphalerite Concentrate Using Ferric Iron in a Redox-controlled Reactor
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Kinetics and Modeling of Chemical Leaching of Sphalerite Concentrate Using Ferric Iron in a Redox-controlled Reactor
Chinese Journal of Chemical EngineeringVol. 21, Issue 8, Pages: 933-9361004-954160545-5(2013)
Affiliations:
1. 2 Department of Pharmacy and Biotechnology, Zibo Vocational Institute,Zibo,China,255314
2. 3 Shandong Provincial Key Lab for Distributed Computer Software Novel Technology, School of Information Science and Engineering, Shandong Normal University,Jinan,China,250014
3. 4 Institute of Agro-products Processing Science and Technology, Xinjiang Academy of Agricultural and Reclamation Science,Shihezi,China,832000
SONG Jian, GAO Ling, LIN Jianqun, WU Hongbin, LIN Jianqiang. Kinetics and Modeling of Chemical Leaching of Sphalerite Concentrate Using Ferric Iron in a Redox-controlled Reactor[J]. Chin.J.Chem.Eng., 2013, 21(8): 933-936.
DOI:
SONG Jian, GAO Ling, LIN Jianqun, WU Hongbin, LIN Jianqiang. Kinetics and Modeling of Chemical Leaching of Sphalerite Concentrate Using Ferric Iron in a Redox-controlled Reactor[J]. Chin.J.Chem.Eng., 2013, 21(8): 933-936.DOI: 10.1016/S1004-9541(13)60545-5.
Kinetics and Modeling of Chemical Leaching of Sphalerite Concentrate Using Ferric Iron in a Redox-controlled Reactor
This work presents a study for chemical leaching of sphalerite concentrate under various constant Fe
3+
concentrations and redox potential conditions. The effects of Fe
3+
concentration and redox potential on chemical leaching of sphalerite were investigated. The shrinking core model was applied to analyze the experimental results. It was found that both the Fe
3+
concentration and the redox potential controlled the chemical leaching rate of sphalerite. A new kinetic model was developed
in which the chemical leaching rate of sphalerite was proportional to Fe
3+
concentration and Fe
3+
/Fe
2+
ratio. All the model parameters were evaluated from the experimental data. The model predictions fit well with the experimental observed values.
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