Preparation of Fe-Mn/K/Al<sub>2</sub>O<sub>3</sub> Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide

F. Fazlollahi; M. Sarkari; H. Gharebaghi; H. Atashi; M. M. Zarei; A. A. Mirzaei; W. C. Hecker

doi:10.1016/S1004-9541(13)60503-0

Your Location：

Home >

Browse articles >

Preparation of Fe-Mn/K/Al₂O₃ Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide

催化、动力学与反应工程 | Updated：2026-01-06

- Preparation of Fe-Mn/K/Al₂O₃ Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide
- Chinese Journal of Chemical Engineering Vol. 21, Issue 5, Pages: 507-5191004-954160503-0(2013)
- Affiliations：
  
  1. 2 South Pars Gas Complex, Asaluyeh, Bushehr,Iran
  2. 3 Department of Chemical Engineering, Faculty of Engineering, University of Sistan & Baluchestan, P.O. Box 98164-161, Zahedan,Iran
  3. 4 Department of Chemistry, Faculty of Science, University of Sistan & Baluchestan, P.O. Box 98135-674, Zahedan,Iran
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(13)60503-0
  CLC：
- Published：2013
- Accepted：
Scan QR Code
O
DOI：

O DOI： 10.1016/S1004-9541(13)60503-0.

摘要

Abstract

A K promoted iron-manganese catalyst was prepared by sol-gel method

and subsequently was tested for hydrogenation of carbon monoxide to light olefins. The kinetic experiments on a well-characterized Fe-Mn/K/Al

catalyst were performed in a fixed-bed micro-reactor in a temperature range of 280-380 ℃

pressure range of 0.1-1.2 MPa

/CO feed molar ratio range of 1-2.1 and a space velocity range of 2000-7200 h

. Considering the mechanism of the process and Langmuir-Hinshelwood-Hogan-Watson (LHHW) approach

unassisted CO dissociation and H-assisted CO dissociation mechanisms were defined. The best models were obtained using non-linear regression analysis and Levenberg-Marquardt algorithm. Consequently

4 models were considered as the preferred models based on the carbide mechanism. Finally

a model was proposed as a best model that assumed the following kinetically relevant steps in the iron-Fischer-Tropsch (FT) synthesis: (1) CO dissociation occurred without hydrogen interaction and was not a rate-limiting step; (2) the first hydrogen addition to surface carbon was the rate-determining steps. The activation energy and adsorption enthal

py were calculated 40.0 and -30.2 kJ·mol

respectively.

关键词

Keywords

references

Views

346

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Kinetics of water-isocyanate reaction in N,N-dimethylformamide

Controllable synthesis of Ni3S2/V3S4@NF-xF(x=0, 4, 8) catalysts for efficient hydrogen production in seawater and urea electrolyte

Synthesis of methyl diphenylmethane dicarbamate by methyl phenylcarbamate condensation catalyzed by NKC-9: Non-phosgene preparation of key precursors for diphenylmethane diisocyanate

CaO-stabilized tetragonal ZrO2 support for high-performance Ni—Fe alloy catalysts in dry reforming of methane

Related Author

Tao Zhao

Dazhong Zhong

Genyan Hao

Guang Liu

Jinping Li

Qiang Zhao

Zhirong Chen

Weitao Yang

Related Institution

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology

College of Chemical and Biological Engineering, Zhejiang University

Department of Chemistry, Xinzhou Normal University

Henan Provincial Key Laboratory of Nanocomposites and Applications, Institute of Nanostructured Functional Materials, Huanghe Science and Technology College

School of Chemistry and Chemical Engineering, North University of China

⁰

Preparation of Fe-Mn/K/Al2O3 Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide

DOI：10.1016/S1004-9541(13)60503-0

摘要

Abstract

关键词

Keywords

references

Preparation of Fe-Mn/K/Al₂O₃ Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide