ZrO<sub>2</sub>/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix

范方强; 夏正斌; 李清英; 李忠; 陈焕钦

doi:10.1016/S1004-9541(13)60448-6

Your Location：

Home >

Browse articles >

ZrO₂/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix

材料与产品工程 | Updated：2026-01-06

- ZrO₂/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix
- Chinese Journal of Chemical Engineering Vol. 21, Issue 2, Pages: 113-1201004-954160448-6(2013)
- Affiliations：
  
  School of Chemistry and Chemical Engineering, South China University of Technology,Guangzhou,China,510640
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(13)60448-6
  CLC：
- Published：2013
- Accepted：
Scan QR Code
/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix[J]. Chinese Journal of Chemical Engineering, 2013, 21(2): 113-120.
DOI：

/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix[J]. Chinese Journal of Chemical Engineering, 2013, 21(2): 113-120. DOI： 10.1016/S1004-9541(13)60448-6.

摘要

Abstract

ZrO

/PMMA nanocomposite particles are synthesized through an in-situ free radical emulsion polymerization based on the silane coupling agent (Z-6030) modified ZrO

nanoparticles

and the morphology

size and its distribution of nanocomposite particles are investigated. Scanning electron microscopy (SEM) images demonstrate that the methyl methacrylate (MMA) feeding rate has a significant effect on the particle size and morphology. When the MMA feeding rate decreases from 0.42 ml·min

-1

to 0.08 ml·min

-1

large particles (about 200-550 nm) will not form

and the size distribution become narrow (36-54 nm). The average nanocomposite particles size increases from 34 nm to 55 nm

as the MMA/ZrO

nanoparticles mass ratio increased from 4︰1 to 16︰1. Regular spherical ZrO

/PMMA nanocomposite particles are synthesized when the emulsifier OP-10 concentration is 2 mg·ml

-1

. The nanocomposite particles could be mixed with VAc-VeoVa10 polymer matrix just by magnetic stirring to prepare the ZrO

/PMMA/VAc-VeoVa10 hybrid coatings. SEM and atomic force microscopy (AFM) photos reveal that the distribution of the ZrO

/PMMA nanocomposite particles in the VAc-VeoVa10 polymer matrix i

s homogenous and stable. Here

the grafted-PMMA polymer on ZrO

nanoparticles plays as a bridge which effectively connects the ZrO

nanoparticles and the VAc-VeoVa10 polymer matrix with improved comparability. In consequence

the hybrid coating with good dispersion stability is obtained.

关键词

Keywords

references

Views

190

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

A core–shell Ni/SiO2@TiO2 catalyst for highly selective one-step synthesis of 2-propylheptanol from n-pentanal

Functional monodisperse microspheres fabricated by solvothermal precipitation co-polymerization

Synthesis and Characterization of Fluorine-containing Polyacrylate Emulsion with Core-Shell Structure

Non-phosgene synthesis processes of isocyanates: One-step and two-step routes

Recovery rubidium chloride and cyclic utilization of hexacyanoferrate(II) ion from hexacyanoferrate-internediate solutions via solvent extraction

Related Author

Hualiang An

Rui Wang

Wenhao Wang

Daolai Sun

Xinqiang Zhao

Yanji Wang

Fenghao Guo

Yuanyuan Ding

Related Institution

Hebei Provincial Key Laboratory of Green Chemical Technology and Efficient Energy Saving, Tianjin Key Laboratory of Chemical Process Safety, School of Chemical Engineering and Technology, Hebei University of Technology

Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan

⁰

ZrO2/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix

DOI：10.1016/S1004-9541(13)60448-6

摘要

Abstract

关键词

Keywords

references

ZrO₂/PMMA Nanocomposites: Preparation and Its Dispersion in Polymer Matrix