L.oil with trace sulfuric acid catalyst(0.02%-0.08% oil) was investigated at 135-184℃.Both esterification and transesterification can be well carried out simultane-ously.Factors affecting the process were investigated
which included the reaction temperature
reaction time
the molar ratio of alcohol to oil
catalyst amount
water content
free fatty acid(FFA) and fatty acid methyl ester(FAME) content.Under the conditions at 165℃
0.06%(by mass) H
2
SO
4
of the oil mass
1.6 MPa and 20:1 methanol/oil ratio
the yield of glycerol reached 84.8% in 2 hours.FFA and FAME showed positive effect on the transesterification in certain extent.The water mass content below 1.0% did not show a noticeable effect on trans-esterification.Reaction kinetics in the range of 155℃ to 175℃ was also measured.
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Related Author
Dong Lu
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Qiuyang Wu
Jiahao Liu
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Li Deng
Kaili Nie
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Related Institution
National Energy R&D Center for Biorefinery, Beijing Key Laboratory of Bioprocess, College of Life Science and Technology, Beijing University of Chemical Technology
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