Dilution on Methane Ignition in Moderate or Intense Low-oxygen Dilution(MILD) Combustion: A Numerical Study[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 701-709.
DOI:
Dilution on Methane Ignition in Moderate or Intense Low-oxygen Dilution(MILD) Combustion: A Numerical Study[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 701-709.DOI: 10.1016/S1004-9541(11)60238-3.
Effects of CO2 Dilution on Methane Ignition in Moderate or Intense Low-oxygen Dilution(MILD) Combustion: A Numerical Study
/air under moderate or intense low-oxygen dilution(MILD) combustion conditions were numerically studied to clarify the fundamental effects of exhaust gas recirculation(EGR)
especially CO
2
in EGR gases
on ignition characteristics.Specifically
effects of CO
2
addition on autoignition delay time were emphasized at temperature between 1200 K and 1600 K for a wide range of the lean-to-rich equivalence ratio(0.2~2).The results showed that the ignition delay time increased with equivalence ratio or CO
2
dilution ratio.Furthermore
ignition delay time was seen to be exponentially related with the reciprocal of initial temperature.Special concern was given to the chemical effects of CO
2
on the ignition delay time.The enhancement of ignition delay time with CO
2
addition can be mainly ascribed to the decrease of H
O and OH radicals.The predictions of temperature profiles and mole fractions of CO and CO
2
were strongly related to the chemical effects of CO
2
.A single ignition time correlation was obtained in form of Arrhenius-type for the entire range of conditions as a function of temperature
CH
4
mole fraction and O
2
mole fraction.This correlation could successfully capture the complex behaviors of ignition of CH
4
/air/CO
2
mixture.The results can be applied to MILD combustion as "reference time"
for example
to
predict ignition delay time in turbulent reacting flow.
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