Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB

江欢欢; 葛小芳; 徐颖华; 张雯雯; 马淳安

doi:10.1016/S1004-9541(11)60154-7

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Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB

Updated：2026-01-06

- Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB
- Chinese Journal of Chemical Engineering Vol. 19, Issue 2, Pages: 199-204(2011)
- Affiliations：
  
  1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology,Hangzhou,China,310032
  2. Shaoxing Environmental Monitoring Central Station,Shaoxing,China,312000
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(11)60154-7
  CLC：
- Published：2011
- Accepted：
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JIANG Huanhuan, GE Xiaofang, XU Yinghua, ZHANG Wenwen, MA Chun'an. Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB[J]. , 2011, 19(2): 199-204.
DOI：

JIANG Huanhuan, GE Xiaofang, XU Yinghua, ZHANG Wenwen, MA Chun'an. Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB[J]. , 2011, 19(2): 199-204. DOI： 10.1016/S1004-9541(11)60154-7.

摘要

Abstract

The indirect electrochemical reduction of Indanthrene Brilliant Green FFB (IBG) was investigated in detail by cyclic voltammetry and electrolytic experiments.Triethanolamine (TEA) was used as ligand to form electrochemically active Fe(Ⅲ)-complexes in alkaline solution.The effects of operating parameters including reaction temperature

current density

concentration of NaOH and Fe(Ⅲ)-TEA mediator had been studied by orthogonal ex-periments and the mechanism of radicals on electrochemical reduction was discussed.The cyclic voltammetry experimental results show that Fe(Ⅲ)-TEA complexes are well suited for the indirect electrochemical reduction of IBG.The electrolytic experiments show that high current efficiency (49.9%) can be successfully achieved under optimized conditions and the current density is found to be the main influence factor.

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