Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase

孙晓英; 赵雪冰; 杜伟; 刘德华

doi:10.1016/S1004-9541(11)60078-5

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Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase

Updated：2026-01-06

- Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase
- Chinese Journal of Chemical Engineering Vol. 19, Issue 6, Pages: 964-971(2011)
- Affiliations：
  
  1. Institute of Applied Chemistry, Department of Chemical Engineering, Tsinghua University,Beijing,China,10084
  2. Institute of Petroleum, General Logistics Department of PLA,Beijing,China,102300
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(11)60078-5
  CLC：
- Published：2011
- Accepted：
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SUN Xiaoying, ZHAO Xuebing, DU Wei, LIU Dehua. Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase[J]. , 2011, 19(6): 964-971.
DOI：

SUN Xiaoying, ZHAO Xuebing, DU Wei, LIU Dehua. Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase[J]. , 2011, 19(6): 964-971. DOI： 10.1016/S1004-9541(11)60078-5.

摘要

Abstract

Performic acid (PFA) is an oxidant used in chemical processing

synthesis and bleaching. The macro kinetic models of synthesis

hydrolysis and decomposition of PFA were investigated

via

formic acid-autocatalyzed reaction. It was found that the intrinsic activation energies of PFA synthesis and hydrolysis were 75.2 kJ·mol

-1

and 40.4 kJ·mol

-1

respectively. The observed activation energy of PFA decomposition was 95.4 kJ·mol

-1

. The experimental results indicated that the decomposition of PFA was liable to occur even at the ambient temperature. Both the spontaneous decomposition and the radical-introduced decomposition contributed to the decomposition of PFA.

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