The adsorption equilibrium of a fluoride solution on 1-2 mm granular activated alumina modified by Fe
2
(SO
4
)
3
-solution was investigated.The experiments were conducted using a wide range of initial fluoride concentrations(0.5 to 180 mg·L
-1
at pH~7.0) and an adsorbent dose of 1.0 g·L
-1
.The application of Langmuir and Freundlich adsorption isotherm models(linear and nonlinear forms) generally showed that a single Langmuir or Freundlich equation cannot fit the entire concentration gap.Experimental data on low equilibrium concentrations(0.1 to 5.0 mg·L
-1
) was in line with both Langmuir and Freundlich isotherm models
whereas that of high equilibrium concentrations(5.0 to 150 mg·L
-1
) was more in line with the Freundlich isotherm model.A new LangmuirFreundlich function was used for the entire concentration gap
as well as for low and high concentrations.
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