Efficient Solvent-free Synthesis of Chloropropene Carbonate from the Coupling Reaction of CO<sub>2</sub> and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts

王梅; 佘远斌; 周贤太; 纪红兵

doi:10.1016/S1004-9541(11)60005-0

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Efficient Solvent-free Synthesis of Chloropropene Carbonate from the Coupling Reaction of CO₂ and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts

催化、动力学与反应工程 | Updated：2026-01-06

- Efficient Solvent-free Synthesis of Chloropropene Carbonate from the Coupling Reaction of CO₂ and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts
- Chinese Journal of Chemical Engineering Vol. 19, Issue 3, Pages: 446-451(2011)
- Affiliations：
  
  School of Chemistry and Chemical Engineering/Key Laboratory of Low-carbon Chemistry&Energy Conservation of Guangdong Province, Sun Yat-sen University,Guangzhou,China,510275
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(11)60005-0
  CLC：
- Published：2011
- Accepted：
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and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts[J]. Chinese Journal of Chemical Engineering, 2011, 19(3): 446-451.
DOI：

and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts[J]. Chinese Journal of Chemical Engineering, 2011, 19(3): 446-451. DOI： 10.1016/S1004-9541(11)60005-0.

摘要

Abstract

Highly efficient solvent-free coupling reaction of carbon dioxide(CO

)and epichlorohydrin catalyzed by meso-tetraphenyl porphyrin magnesium(MgTPP)in the presence of triethylamine as co-catalysts is reported.As a chlorophyll-like catalyst

MgTPP showed excellent activity for the coupling reaction of CO

and epichlorohydrin to chloropropene carbonate

in which the turnover number could reach up to 9200.Moreover

different factors including the amount of catalyst

reaction temperature

pressure and time were systematically investigated and the optimal reaction conditions were obtained(epichlorohydrin 50 mmol

MgTPP 5.0×10

-3

mmol

triethylamine 6.25×10

-3

mmol

140℃

1.5 MPa

8 h).A plausible two-pathway mechanism for the coupling reaction of CO

and epichlorohydrin is proposed to propound the catalysis of MgTPP.

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Efficient Solvent-free Synthesis of Chloropropene Carbonate from the Coupling Reaction of CO2 and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts

DOI：10.1016/S1004-9541(11)60005-0

摘要

Abstract

关键词

Keywords

references

Efficient Solvent-free Synthesis of Chloropropene Carbonate from the Coupling Reaction of CO₂ and Epichlorohydrin Catalyzed by Magnesium Porphyrins as Chlorophyll-like Catalysts