WU Chengli, CAO Yan, DONG Zhongbing, PAN Weiping. Impacting Factors of Elemental Mercury Re-emission across a Lab-scale Simulated Scrubber[J]. , 2010, 18(3): 523-528.
DOI:
WU Chengli, CAO Yan, DONG Zhongbing, PAN Weiping. Impacting Factors of Elemental Mercury Re-emission across a Lab-scale Simulated Scrubber[J]. , 2010, 18(3): 523-528.DOI: 10.1016/S1004-9541(10)60253-4.
Impacting Factors of Elemental Mercury Re-emission across a Lab-scale Simulated Scrubber
)re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury(Hg
2+
)standard solution was injected into the simulated scrubber at a desired rate to simulate absorbing and dissolving of Hg
2+
in the flue gas across wet flue gas desulfurization(WFGD)systems. PS analytical mercury analyzer was used to continuously determine Hg0re-emission concentrations in the carrier gas from the scrubber.Sulfite ion in the slurry of CaSO
3
was validated to reduce Hg
2+
to Hg
0
while no Hg
0
re-emission occurred from slurries of CaSO
4
and CaO.Transitional metal ions with low chemical valence such as Fe
2+
Pb
2+
Ni
2+
AsO
2
-+
-1.Reduction reaction of Hg
2+
to Hg
0
was observed from these solutions.Reduction capabilities for the different transitional metal ions in the solutions were:Pb
2+
Cu
+
Fe
2+
AsO
2
-
Ni
2+
.
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