Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

舒庆; 高继贤; 廖玉会; 王金福

doi:10.1016/S1004-9541(09)60193-2

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Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

Updated：2026-01-06

- Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst
- Chinese Journal of Chemical Engineering Vol. 19, Issue 1, Pages: 163-168(2011)
- Affiliations：
  
  1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University,Beijing,China,100084
  2. School of Material and Chemical Engineering, Jiangxi University of Science and Technology,Ganzhou,China,341000
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(09)60193-2
  CLC：
- Published：2011
- Accepted：
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SHU Qing, GAO Jixian, LIAO Yuhui, WANG Jinfu. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. , 2011, 19(1): 163-168.
DOI：

SHU Qing, GAO Jixian, LIAO Yuhui, WANG Jinfu. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. , 2011, 19(1): 163-168. DOI： 10.1016/S1004-9541(09)60193-2.

摘要

Abstract

The kinetics of simultaneous transesterification and esterification with a carbon-based solid acid catalyst was studied.Two solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt.These catalysts were characterized on the basis of elemental analysis

acidity site concentration

the Brunauer-Emmett-Teller(BET)surface area and pore size.The kinetic parameters with the two catalysts were determined

and the reaction system can be described as a pseudo homogeneous catalyzed reaction.All the forward and reverse reactions follow second order kinetics.The calculated concentration values from the kinetic equations are in good agreement with experimental values.

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