-supported high-activity Ziegler-Natta catalysts for the polymerization of ethylene.In particular
two types of catalysts were investigated
which were N-catalyst(BRICI)and improved polyethylene catalyst.The effects of catalyst structure on kinetic behavior were examined.The distribution of active centers in these catalysts was investigated by energy dispersive analysis by X-rays(EDAX)
and morphologies of catalyst particles and polymer products were examined by scanning electron microscope(SEM).Hydrogen response and copolymerization performance were investigated and compared with the two catalysts.The results were correlated with the kinetic behavior of the two catalysts and appropriate models for polymer particle growth were presented.The improved polyethylene catalyst showed higher activity
better hydrogen response and copolymerization performance.
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Related Author
郭子芳
陈伟
周俊领
杨红旭
Related Institution
Department of Material Science and Engineering, Beijing University of Chemical Technology
Sinopec Beijing Research Institute of Chemical Industry