Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology

张迪; 张鹏远; 邹海魁; 初广文; 毋伟; 朱忠武; 邵磊; 陈建峰

doi:10.1016/S1004-9541(09)60138-5

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Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology

Updated：2026-01-06

- Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology
- Chinese Journal of Chemical Engineering Vol. 18, Issue 5, Pages: 848-855(2010)
- Affiliations：
  
  Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology,Beijing,China,100029
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(09)60138-5
  CLC：
- Published：2010
- Accepted：
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ZHANG Di, ZHANG Pengyuan, ZOU Haikui, CHU Guangwen, WU Wei, ZHU Zhongwu, SHAO Lei, CHEN Jianfeng. Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology[J]. , 2010, 18(5): 848-855.
DOI：

ZHANG Di, ZHANG Pengyuan, ZOU Haikui, CHU Guangwen, WU Wei, ZHU Zhongwu, SHAO Lei, CHEN Jianfeng. Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology[J]. , 2010, 18(5): 848-855. DOI： 10.1016/S1004-9541(09)60138-5.

摘要

Abstract

With the application of HIGEE process intensification technology

petroleum sulfonate surfactant used for enhanced oil recovery was synthesized from petroleum fraction of Shengli crude oil with three sulfonating agents

including diluted liquid sulfur trioxide

diluted gaseous sulfur trioxide and fuming sulfuric acid. For each sulfonating agent

different operation modes (liquid-liquid or gas-liquid reaction with semi-continuous or continuous operation) were applied. The effects of various experimental conditions

such as solvent/oil mass ratio

sulfonating agent/oil mass ratio

gas/liquid ratio

gas concentration

reaction temperature

rotating speed

circulation ratio

reaction time and aging time

on the content of active matter and unsulfonated oil were investigated. Under relatively optimal reaction conditions

the target product was prepared with high mass content of active matter (up to 45.3%) and extremely low oil/water interfacial tension (4.5×10

-3

mN·m

-1

). The product quality and process efficiency are higher compared with traditional sulfonation technology.

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