Preparation and Characterization of γ-Al2O3 by Polyaluminum Chloride with High Al13 Content
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Preparation and Characterization of γ-Al2O3 by Polyaluminum Chloride with High Al13 Content
Chinese Journal of Chemical EngineeringVol. 18, Issue 2, Pages: 333-336(2010)
Affiliations:
1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences,Beijing,China,100085
2. The Equipment Research Institute of PLA's Second Artillery,Beijing,China,100085
In this paper a polyaluminum chloride solution with high Al
13
content was prepared and used as raw material for preparation of γ-Al
2
O
33
·H
2
O and NaOH had little effect on the alumina sample formation.The impurities of NH
4
Cl and NaCl in solution can be removed through repeated washing by EDX analysis.Calcination temperature had a significant effect on alumina crystal phase.The alumina sample can transform completely toγ-Al
2
O
3
in the subsequent heating from 600℃ to 800℃.It is very interesting that Al
13
can be existed inγ-Al
2
O
3
phase even after calcinations.The results indicate that polyaluminum chloride with high Al
13
content is an effective material to prepareγ-Al
2
O
3
.
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