Asghar Molaei Dehkordi, Mohammad Amin Sobati, Mohammad Ali Nazem. Oxidative Desulfurization of Non-hydrotreated Kerosene Using Hydrogen Peroxide and Acetic Acid[J]. , 2009, 17(5): 869-874.
DOI:
Asghar Molaei Dehkordi, Mohammad Amin Sobati, Mohammad Ali Nazem. Oxidative Desulfurization of Non-hydrotreated Kerosene Using Hydrogen Peroxide and Acetic Acid[J]. , 2009, 17(5): 869-874.DOI: 10.1016/S1004-9541(08)60289-X.
Oxidative Desulfurization of Non-hydrotreated Kerosene Using Hydrogen Peroxide and Acetic Acid
The oxidative desulfurization of a real refinery feedstock (i.e.
non-hydrotreated kerosene with total sulfur mass content of 0.16%) with a mixture of hydrogen peroxide and acetic acid was studied.The influences of various operating parameters including reaction temperature (
T
)
acid to sulfur molar ratio (
n
acid
/
n
S
)
and oxidant to sulfur molar ratio (
n
O
/
n
S
) on the sulfur removal of kerosene were investigated.The results revealed that an increase in the reaction temperature (
T
) and nacid/nS enhances the sulfur removal.Moreover
there is an optimum
n
O
/
n
S
related to the reaction temperature and the best sulfur removal could be obtained at
n
O
/
n
S
=8 and 23 for the reaction temperatures of 25 and 60℃
respectively.The maximum observed sulfur removal in the present oxidative desulfurization system was 83.3%.
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