Kinetic Study of Esterification of Lactic Acid with Isobutanol and <i>n</i>-Butanol Catalyzed by Ion-exchange Resins

屈一新; 彭少君; 王水; 张志强; 王际东

doi:10.1016/S1004-9541(08)60276-1

Your Location：

Home >

Browse articles >

Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins

Updated：2026-01-06

- Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins
- Chinese Journal of Chemical Engineering Vol. 17, Issue 5, Pages: 773-780(2009)
- Affiliations：
  
  Beijing Key Laboratory of Bioprocess, Department of Chemical Engineering, Beijing University of Chemical Technology,Beijing,China,100029
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(08)60276-1
  CLC：
- Published：2009
- Accepted：
Scan QR Code
-Butanol Catalyzed by Ion-exchange Resins[J]. , 2009, 17(5): 773-780.
DOI：

-Butanol Catalyzed by Ion-exchange Resins[J]. , 2009, 17(5): 773-780. DOI： 10.1016/S1004-9541(08)60276-1.

摘要

Abstract

The esterification reactions of lactic acid with isobutanol and

-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009.The influences of catalyst loading

stirrer speed

catalyst particle size

initial reactant molar ratio and temperature on the reaction rate have been examined.Experimental kinetic data were correlated by using the Pseudo-homogeneous

Langmuir-Hinshelwood and Eley-Rideal models.Nonideality of the liquid phase was taken into account by using activities instead of molar fractions.The activity coefficients were calculated according to the group contribution method UNIFAC.Provided that the nonideality of the liquid is taken into account

the esterification kinetics of lactic acid with isobutanol and n-butanol catalyzed by the acid ion-exchange resin can be described using all three models with reasonable errors.

关键词

Keywords

references

Views

226

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Reaction kinetics for the heterogeneously resin-catalyzed and homogeneously self-catalyzed esterification of thioglycolic acid with 2-ethyl-1-hexanol

Complete kinetic model for esterification reaction of lauric acid with glycerol to synthesize glycerol monolaurate

Esterification of acetic acid with isobutanol catalyzed by ionic liquid n-sulfopropyl-3-methylpyridinium trifluoromethanesulfonate: Experimental and kinetic study

Liquid-phase esterification of methacrylic acid with methanol catalyzed by cation-exchange resin in a fixed bed reactor: Experimental and kinetic studies

Preparation of solid acid catalyst SO42-/TiO2/γ-Al2O3 for esterification: A study on catalytic reaction mechanism and kinetics

Related Author

Xiaoda Wang

Wenkai Li

Shiwei Wang

Qinglian Wang

Ling Li

Hongxing Wang

Ting Qiu

Han-Qiao Hu

Related Institution

Engineering Research Center of Reactive Distillation, Fujian Province University, School of Chemical Engineering, Fuzhou University

College of Chemical Engineering and Materials Science, Tianjin University of Science & Technology

Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology

Petrochemical Research Institute, China National Petroleum Corporation

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology

⁰

Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins

DOI：10.1016/S1004-9541(08)60276-1

摘要

Abstract

关键词

Keywords

references