WANG Chunfeng, LI Jiansheng, WANG Lianjun, SUN Xiuyun, HUANG Jiajia. Adsorption of Dye from Wastewater by Zeolites Synthesized from Fly Ash:Kinetic and Equilibrium Studies[J]. , 2009, 17(3): 513-521.
DOI:
WANG Chunfeng, LI Jiansheng, WANG Lianjun, SUN Xiuyun, HUANG Jiajia. Adsorption of Dye from Wastewater by Zeolites Synthesized from Fly Ash:Kinetic and Equilibrium Studies[J]. , 2009, 17(3): 513-521.DOI: 10.1016/S1004-9541(08)60239-6.
Adsorption of Dye from Wastewater by Zeolites Synthesized from Fly Ash:Kinetic and Equilibrium Studies
in aqueous solution was investigated by adsorption process on single-phase and high-crystalline zeolite A (FA-ZA) and X (FA-ZX). Both adsorbents FA-ZA and FA-ZX were synthesized from fly ash prepared aluminosilicate gel followed by the hydrothermal treatment at 100℃ with the control of Si/Al molar ratio
respectively. The properties of the synthetic zeolites and commercial grade zeolites
such as thermal stability
elemental composition
and cation exchange capacity
were investigated for comparison. Batch method was used to study the influential parameters
such as initial pH value of the solution
temperatures
and adsorbents dosage
on the adsorption process. The experimental data were well fitted by Ho’ pseudo-second-order model and liquid film diffusion model. The suitability of Langmuir and Freundlich isotherms to the equilibrium data was investigated in the solid-liquid system while the Langmuir model produces the best results. Thermodynamic data (△
H
△
S
and △
G
) corresponding to the MB uptake were evaluated from the Langmuir model. In all the adsorption experiments
the adsorption capacity followed the order as follows:FA-ZXFA-ZA. In addition
attempts were also made to regenerate the adsorbents.
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