Investigation of Nitration Processes of <i>iso</i>-Octanol with Mixed Acid in a Microreactor

沈佳妮; 赵玉潮; 陈光文; 袁权

doi:10.1016/S1004-9541(08)60225-6

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Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor

Updated：2026-01-06

- Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor
- Chinese Journal of Chemical Engineering Vol. 17, Issue 3, Pages: 412-418(2009)
- Affiliations：
  
  1. Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,China,116023
  2. Graduate University, Chinese Academy of Sciences,Beijing,China,100049
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(08)60225-6
  CLC：
- Published：2009
- Accepted：
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-Octanol with Mixed Acid in a Microreactor[J]. , 2009, 17(3): 412-418.
DOI：

-Octanol with Mixed Acid in a Microreactor[J]. , 2009, 17(3): 412-418. DOI： 10.1016/S1004-9541(08)60225-6.

摘要

Abstract

In this paper

the nitration characteristic of alcohols with mixed acid for the synthesis of energetic materials in a stainless steel microreactor was investigated experimentally. The nitration of

iso

-octanol with HNO

-H

mixed acid was chosen as a typical model reaction which involved fast and strong exothermic liquid-liquid heterogeneous reaction process. The influences of mixed acid composition

flow rate

organic/aqueous flow ratio and reaction temperature have been investigated. The results indicated that the reaction could be conducted safely and stably in the microreactor at 25-40℃

which are enhanced compared to 15℃ or below for safe operating conditions in the conventional reactors. Moreover

the 98.2% conversion of

iso

-octanol could be obtained and no by-products were detected in all cases.

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Related Institution

Dalian Institute of Chemical Physics, Chinese Academy of Sciences

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⁰

Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor

DOI：10.1016/S1004-9541(08)60225-6

摘要

Abstract

关键词

Keywords

references