Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

梁英华; 郭红霞; 陈红萍; 吕敬德; 张波波

doi:10.1016/S1004-9541(08)60223-2

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Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

Updated：2026-01-06

- Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol
- Chinese Journal of Chemical Engineering Vol. 17, Issue 3, Pages: 401-406(2009)
- Affiliations：
  
  1. School of Chemical Engineering and Biological Technology, Hebei Polytechnic University,Tangshan,China,063009
  2. College of Light Industry, Hebei Polytechnic University,Tangshan,China,063000
  3. Tangshan Zhongrun Coal Chemical Co., Ltd.,Tangshan,China,063611
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(08)60223-2
  CLC：
- Published：2009
- Accepted：
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LIANG Yinghua, GUO Hongxia, CHEN Hongping, LÜJingde, ZHANG Bobo. Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol[J]. , 2009, 17(3): 401-406.
DOI：

LIANG Yinghua, GUO Hongxia, CHEN Hongping, LÜJingde, ZHANG Bobo. Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol[J]. , 2009, 17(3): 401-406. DOI： 10.1016/S1004-9541(08)60223-2.

摘要

Abstract

Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas

crystal phase

valency

and content of the element on the surface of the catalysts were determined

and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce

and the yields of DPC for the two catalysts can reach 30% and 23%

respectively. However

doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and

-bromophenyl phenyl carbonate.

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