Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries

Deqing He; Zihao Xie; Qian Yang; Wei Wang; Chao Su

Your Location：

Home >

Browse articles >

Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries

Updated：2026-01-06

- Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries
- Chinese Journal of Chemical Engineering Vol. 67, Issue 3, Pages: 58-67(2024)
- Affiliations：
  
  1. School of Energy and Power, Jiangsu University of Science and Technology,Zhenjiang,China,212100
  2. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University,Nanjing,China,211816
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：2024
- Accepted：
Scan QR Code
Deqing He, Zihao Xie, Qian Yang, Wei Wang, Chao Su. Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 58-67.
DOI：

Deqing He, Zihao Xie, Qian Yang, Wei Wang, Chao Su. Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 58-67. DOI：

摘要

Abstract

The sluggish redox kinetics of polysulfides in lithiumesulfur (LieS) batteries are a significant obstacle to their widespread adoption as energy storage devices. However

recent studies have shown that tungsten oxide (WO

) can facilitate the conversion kinetics of polysulfides in LieS batteries. Herein

we fabricated host materials for sulfur using nitrogen-doped carbon nanotubes (N-CNTs) and WO

. We used low-cost components and simple procedures to overcome the poor electrical conductivity that is a disadvantage of metal oxides. The composites of WO

and N-CNTs (WO

/N-CNTs) create a stable framework structure

fast ion diffusion channels

and a 3D electron transport network during electrochemical reaction processes. As a result

the WO

/N-CNT-Li

cathode demonstrates high initial capacity (1162 mA·h·g

-1

at≥0.5 C)

excellent rate performance (618 mA·h·g

-1

at 5.5 C)

and a low capacity decay rate (0.093% up to 600 cycles at 2 C). This work presents a novel approach for preparing tungsten oxide/carbon composite catalysts that facilitate the redox kinetics of polysulfide conversion.

关键词

Keywords

references

Views

141

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Controllable synthesis of Ni3S2/V3S4@NF-xF(x=0, 4, 8) catalysts for efficient hydrogen production in seawater and urea electrolyte

Bio-templated graphitic carbon architectures enable high-rate and durable LiFePO4 cathodes for sustainable lithium-ion batteries

Dual-charged, non-swelling amine/carboxyl functionalized Fe—Mn mixed oxide composite for simultaneous removal of anionic and cationic azo dyes: Experimental and DFT studies

Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO2 particles prepared by facile spraying technique

Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

Related Author

Wen Wei

Meng Xiangyu

Liu Min

Du Xiaoqiang

Zhang Xiaoshuang

Li Bingbing

Xu Yue

Chen Chen

Related Institution

School of Environment and Safety Engineering, North University of China

School of Chemistry and Chemical Engineering, North University of China

Henan Provincial Key Laboratory of Nanocomposites and Applications, Institute of Nanostructured Functional Materials, Huanghe Science and Technology College

Department of Chemistry, Xinzhou Normal University

Institute of Ion-Plasma and Laser Technologies, Uzbekistan Academy of Sciences, Tashkent

⁰