Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction

Yifan Jiang; Bingqi Xie; Jisong Zhang

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Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction

Full Length Article | Updated：2026-01-06

- Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction
- Chinese Journal of Chemical Engineering Vol. 60, Issue 8, Pages: 165-172(2023)
- Affiliations：
  
  State Key Lab of Chemical Engineering, Department of Chemical Engineering, Tsinghua University,Beijing,China,100084
- Author bio：
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- DOI：
  CLC：
- Published：2023
- Accepted：
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Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction[J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 165-172.
DOI：

Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction[J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 165-172. DOI：

摘要

Abstract

Suzuki-Miyaura reaction of aryl halides with phenylboronic acid using a heterogeneous palladium catalyst based on activated carbons (AC) was systematically investigated in this work. Two different reaction modes (batch procedure and continuous-flow procedure) were used to study the variations of reaction processing. The heterogeneous catalysts presented excellent reactivity and recyclability for iodobenzene and bromobenzene substrates in batch mode

which can be attributed to stabilization of Pd nanoparticles by the thiol and amino groups on the AC supports. However

significant dehalogenation in the reaction mixture and Pd leaching from the heterogeneous catalysts were observed in continuous-flow mode. This unique phenomenon in continuous-flow mode resulted in a dramatic decline in reaction selectivity and durability of heterogeneous catalysts comparing with that of batch mode. In addition

the heterogeneous Pd catalysts with thiol- and amino-modified AC supports exhibited different reactivity and durability in batch and continuous-flow mode owing to the difference of interaction between Pd species and AC supports.

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