Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant
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Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant
Chinese Journal of Chemical EngineeringVol. 48, Issue 8, Pages: 202-210(2022)
Affiliations:
1. School of Energy and Power Engineering, Shandong University,Jinan,China,250061
2. Huadian Electric Power Research Institute Co., Ltd.,Hangzhou,China,310030
Author bio:
Funds:
DOI:
CLC:
Published:2022
Accepted:
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Kai Zhang, Fangming Xue, Zhiqiang Wang, Xingxing Cheng. Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant[J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 202-210.
DOI:
Kai Zhang, Fangming Xue, Zhiqiang Wang, Xingxing Cheng. Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant[J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 202-210.DOI:
Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant
Ammonium bisulfate (ABS) is a viscous compound produced by the escape NH
3
in the NO reduction process and SO
3
in the flue gas at a certain temperature
which can cause the ash corrosion of the air preheater in coal-fired power plants. Therefore
it is essential to study the formation temperature of ABS to prevent the deposition of ABS in air preheaters. In this paper
the SO
3
reaction kinetic model is used to analyze the SO
3
generation process from coal combustion to the selective catalytic reduction (SCR) exit stage
and the kinetic model of NO reduction is used to analyze the NH
3
escape process. A prediction model for calculating the ABS formation temperature based on the S content in coal and NO reduction parameters of the SCR is proposed
solving the difficulty of measuring SO
3
concentration and NH
3
concentration in the previous calculation equation of ABS formation temperature. And the reliability of the model is verified by the actual data of the power plant. Then the influence of S content in coal
NH
3
/ NO
x
molar ratio
different NO
x
concentrations at SCR inlet
and NO removal efficiency on the formation temperature of ABS are analyzed.
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