High-temperature CO2 sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor
Separation Science and Engineering|Updated:2026-01-06
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High-temperature CO2 sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor
Chinese Journal of Chemical EngineeringVol. 50, Issue 10, Pages: 177-184(2022)
Affiliations:
Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University,Tianjin,China,300072
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Published:2022
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sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. 中国化学工程学报, 2022, 50(10): 177-184.
DOI:
sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. 中国化学工程学报, 2022, 50(10): 177-184.DOI:
High-temperature CO2 sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor
increased rapidly because of the growing use of fossil fuels. And CaO sorbents possess the capability to be used in capture of CO
2
at high temperature. In the work
Ca—Al complex oxides derived from citrate and stearate intercalated layered double hydroxides were fabricated and their CO
2
adsorption capacity was compared with that from CO
3
2-
intercalated layered double hydroxides. The results presented that the sorbents (Ca/Al = 5) with Ca—Al—citrate layered double hydroxides as precursors performed best and displayed remarkable CO
2
capture capacity of 52.0% (mass) at the carbonization temperature of 600 ℃ without distinct recession during cycling adsorption/desorption tests. The excellent CO
2
adsorption capacity of the sorbent was ascribed to its smaller crystallite size of calcinated particles
optimized pore size distribution as well as homogeneous distributed Ca and Al in the sorbent.
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